Synthesis, Structure, and Reactivity of a Bis(silylene)carbonylruthenium Complex and a Novel Addition Reaction of Photochemically Generated Dimethylsilylene to Bis(silylene) Complexes Cp(OC)M{SiMe2···O(Me)···SiMe2} (M = Ru, Fe)
Author:
Affiliation:
1. Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om980164c
Reference50 articles.
1. Organometalloidal derivatives of the transition metals. 12. Polysilane-metal interactions. Photochemical deoligomerizations and base treatment migrations from iron to cyclopentadienyl ligands
2. Organometalloidal derivatives of transition metals. Part XXI. Synthesis and photochemical deoligomerizations of a series of isomeric disilyl iron complexes: (.eta.5-C5H5)Fe(CO)2Si2Ph3-nMe2+n)
3. Photochemical skeletal redistributions of permethylated linear and cyclic oligosilyl groups in (.eta.5-C5H5)Fe(CO)2-substituted oligosilanes
4. Organometalloidal derivatives of the transition metals. 24. Synthesis and photochemical reactivity of transition-metal-disubstituted disilanes LMSiMe2SiMe2ML (LM = (.eta.5-C5H5)Fe(CO)2 and (.eta.5-C5H5)Fe(.eta.5-C5H4))1
5. Photochemical treatment of transition metal substituted disilanes, (.eta.5-C5H5)Fe(CO)2Si2Me4(C6H4X) (X = Cl, CF3, NMe2, OMe, H), including trapping of expelled silylene
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4. Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring;Dalton Transactions;2017
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