Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring-Reference-Cited by-同舟云学术

Hydrogen-bridged bis(silylene) complexes of ruthenium and iron: synthesis, structures and multi-centre bonding interactions at the M–Si–H–Si four-membered ring

Published:2017 Issue:27 Volume:46 Page:8701-8704
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Hashimoto Hisako¹²³⁴⁵^ORCID,Komura Katsuto¹²³⁴⁵,Ishizaki Takatoshi¹²³⁴⁵,Odagiri Yuto¹²³⁴⁵,Tobita Hiromi¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Tohoku University

4. Sendai

5. Japan

Abstract

Ruthenium and iron complexes featuring a MSi₂H four-centre bonding interaction were synthesized and the interaction was evaluated experimentally and theoretically.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00505A

Reference20 articles.

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3. A Silyl Cation with a Three-Center Si-H-Si Bond

4. Hydrogen- and Fluorine-Bridged Disilyl Cations and Their Use in Catalytic C−F Activation

5. Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand

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