Syntheses; 77Se, 203Tl, and 205Tl NMR; and Theoretical Studies of the Tl2Se66-, Tl3Se65-, and Tl3Se75- Anions and the X-ray Crystal Structures of [2,2,2-crypt-Na]4[Tl4Se8]·en and [2,2,2-crypt-Na]2[Tl2Se4]∞1·en-Reference-Cited by-同舟云学术

Syntheses; 77Se, 203Tl, and 205Tl NMR; and Theoretical Studies of the Tl2Se66-, Tl3Se65-, and Tl3Se75- Anions and the X-ray Crystal Structures of [2,2,2-crypt-Na]4[Tl4Se8]·en and [2,2,2-crypt-Na]2[Tl2Se4]∞1·en

Published:2005-10-28 Issue:24 Volume:44 Page:8770-8785
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Pirani Ayaaz M.¹,Mercier Hélène P. A.¹,Suontamo Reijo J.¹,Schrobilgen Gary J.¹,Santry David P.¹,Borrmann Horst¹

Affiliation:

1. Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada, Department of Chemistry, University of Jyväskylä, P.O. Box 35, FIN-40014, Finland, and Max-Planck-Institut für Chemische Physik fester Stoffe, Raum B1.2.11, Nöthnitzer Strasse 40, Dresden D-01187, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic0510922

Reference50 articles.

1. First Examples of Thallium Chalcogenide Cages. Syntheses, 77Se, 203Tl, and 205Tl NMR Study of the Tl4Se54- and Tl4Se64- Anions, the X-ray Crystal Structure of (2,2,2-crypt-K+)3Tl5Se53-, and Theoretical Studies

2. Tl2Ch22- (Ch = Se and/or Te) Anions: X-ray Crystal Structures and Raman Spectra of (2,2,2-crypt-K+)2Tl2Se22- and (2,2,2-crypt-K+)2Tl2Te22- and Solution 77Se, 203Tl, and 205Tl NMR Spectroscopic and Theoretical Studies of Tl2Ch22-, In2Se22-, and In2Te22-

3. Preparation and multinuclear magnetic resonance study of the Zintl anions, HgCh22-, CdCh22-, SnCh32-, TlCh33-, SnCh44-, and Tl2Ch22- (Ch = Se and/or Te). Chemical shift and coupling constant correlations

4. Novel adamantane-like thio- and selenoanions from aqueous solution: Ga4S108−, In4S108−, In4Se108−

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