First Examples of Thallium Chalcogenide Cages. Syntheses, 77Se, 203Tl, and 205Tl NMR Study of the Tl4Se54- and Tl4Se64- Anions, the X-ray Crystal Structure of (2,2,2-crypt-K+)3Tl5Se53-, and Theoretical Studies-Reference-Cited by-同舟云学术

First Examples of Thallium Chalcogenide Cages. Syntheses, 77Se, 203Tl, and 205Tl NMR Study of the Tl4Se54- and Tl4Se64- Anions, the X-ray Crystal Structure of (2,2,2-crypt-K+)3Tl5Se53-, and Theoretical Studies

Published:2000-12-14 Issue:2 Volume:40 Page:233-254
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Campbell Janette¹,Mercier Hélène P. A.¹,Santry David P.¹,Suontamo Reijo J.¹,Borrmann Horst¹,Schrobilgen Gary J.¹

Affiliation:

1. Department of Chemistry, McMaster University, Hamilton, Ontario L8S 4M1, Canada; Snowbird Software, Inc., 71A Leland Street, Hamilton, Ontario, L8S 3A1, Canada; Department of Chemistry, University of Jyväskylä, P.O. Box 35, FIN-40351 Jyväskylä, Finland; and Max-Planck-Institut für Chemische Physik fester Stoffe, Raum B1.2.11, Nöthnitzer Strasse 40, Dresden D-01187, Germany

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic000779d

Reference58 articles.

1. Heteroatomic polyanions of post-transition metals. Synthesis and structure of dithalliumditellurium(2-), Tl2Te22-. Skeletal requirements for bonding

2. Tl2Ch22- (Ch = Se and/or Te) Anions: X-ray Crystal Structures and Raman Spectra of (2,2,2-crypt-K+)2Tl2Se22- and (2,2,2-crypt-K+)2Tl2Te22- and Solution 77Se, 203Tl, and 205Tl NMR Spectroscopic and Theoretical Studies of Tl2Ch22-, In2Se22-, and In2Te22-

3. Polyselenide chemistry of indium and thallium in dimethylformamide, acetonitrile, and water. Syntheses, structures, and properties of the new complexes [In2(Se4)2(Se5)]4-, [In2Se2(Se4)2]2-, and [In3Se3(Se4)3]3-

4. Synthesis of [Tl4Se16]4−: a novel tetranuclear Tl3+ polyselenide

5. Open Framework Structures Based on Se x 2– Fragments: Synthesis of (Ph 4 P)[M(Se 6 ) 2 ] (M = Ga, In, TI) in Molten (Ph 4 P) 2 Se x

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