Sterically Encumbered (Perfluoroaryl) Borane and Aluminate Cocatalysts for Tuning Cation−Anion Ion Pair Structure and Reactivity in Metallocene Polymerization Processes. A Synthetic, Structural, and Polymerization Study
Author:
Affiliation:
1. Contribution from the Department of Chemistry, Northwestern University, Evanston, Illinois 60208-3113
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja973769t
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1. The formation and structures of the methyl-bridged complexes Cp∗TiMe2(μ-Me)B(C6F5)3 and [Cp∗TiMe2(μ-Me)TiMe2Cp∗][MeB(C6F5)3]
2. Intrinsic Ancillary Ligand Effects in Cationic Zirconium Polymerization Catalysts: Gas-Phase Reactions of [L2ZrCH3]+ Cations with Alkenes
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