Mechanism of cationic ring-opening polymerisation of ε-caprolactone using metallocene/borate catalytic systems: a DFT and NCI study on chain initiation, propagation and termination-Reference-Cited by-同舟云学术

Mechanism of cationic ring-opening polymerisation of ε-caprolactone using metallocene/borate catalytic systems: a DFT and NCI study on chain initiation, propagation and termination

Published:2024 Issue:17 Volume:14 Page:11715-11727
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Meelua Wijitra¹²,Linnolahti Mikko³^ORCID,Jitonnom Jitrayut²^ORCID

Affiliation:

1. Demonstration School, University of Phayao, Phayao 56000, Thailand

2. Unit of Excellence in Computational Molecular Science and Catalysis, and Division of Chemistry, School of Science, University of Phayao, Phayao 56000, Thailand

3. Department of Chemistry, University of Eastern Finland Joensuu Campus, Yliopistokatu 7, FI-80100 Joensuu, Finland

Abstract

DFT and NCI studies provide a detailed mechanism of cationic ROP of ε-caprolactone by metallocene/borate catalysts and capture weak interactions at the contacts between the borate counteranions and the cationic species.

Funder

Thailand Science Research and Innovation

University of Phayao

Research Council of Finland

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/RA/D4RA01178C

Reference62 articles.

1. Current Applications of Polycaprolactone as a Scaffold Material for Heart Regeneration

2. Poly-ε-caprolactone (PCL), a promising polymer for pharmaceutical and biomedical applications: Focus on nanomedicine in cancer

3. Sustainable drug release from polycaprolactone coated chitin-lignin gel fibrous scaffolds

4. Synthesis and Properties of Functionalized Poly(ε-caprolactone); Chain Polymerization Followed by Polycondensation in One Pot with Initiator and Catalyst in One Molecule. Synthesis and Molecular Structures

5. Recent advances in the synthesis of aliphatic polyesters by ring-opening polymerization☆

Cited by 1 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Catalytic dehydrogenation for hydrogen production controlled by metal-supported heterogeneous catalysts;Catalysis Science & Technology;2024