Phosphine-Catalyzed Synthesis of 1,3-Dioxan-4-ylidenes

Author:

Zhu Xue-Feng1,Henry Christopher E.1,Wang Jay1,Dudding Travis1,Kwon Ohyun1

Affiliation:

1. Department of Chemistry and Biochemistry, University of California, Los Angeles, 607 Charles E. Young Drive East, Los Angeles, California 90095-1569

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference17 articles.

1. Reactions of Electron-Deficient Alkynes and Allenes under Phosphine Catalysis

2. An Expedient Phosphine-Catalyzed [4 + 2] Annulation:  Synthesis of Highly Functionalized Tetrahydropyridines

3. A new aldol condensation of .alpha.-allenic esters with aldehydes, including a one-pot synthesis of enyne compounds

4. Phosphine-catalyzed [3+2] cycloaddition reaction of methyl 2,3-butadienoate and N-tosylimines. A novel approach to nitrogen heterocycles

5. The connectivity and relative stereochemistry of these compounds were confirmed by X-ray crystallographic analysis. Crystallographic data for3-Eand3-Zhave been deposited with the Cambridge Crystallographic Data Centre as supplementary numbers CCDC 250757 and 250758. CCDC 250757 and 250758 contain the supplementary crystallographic data for this paper. These data can be obtained online free of charge (or from the Cambridge Crystallographic Data Center, 12, Union Road, Cambridge CB2 1EZ, U.K. fax:  (+44) 1223-336-033; or deposit@ccdc.cam.ac.uk).

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