Lithiated Oppolzer Enolates: Solution Structures, Mechanism of Alkylation, and Origin of Stereoselectivity
Author:
Affiliation:
1. Department of Chemistry and Chemical Biology Baker Laboratory, Cornell University Ithaca, New York 14853-1301, United States
Funder
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/jacs.2c09341
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5. A survey of approximately 700 total syntheses compiled by H. J. Reich and co-workers revealed LDA to be the most commonly used reagent. The database currently resides at: The Hans Reich’s Collection. https://organicchemistrydata.org/hansreich/resources/syntheses/?index=groupby%2Finformation&page=acknowledgment%2F (accessed 2021-10-23).
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1. Lithium, sodium and potassium enolate aggregates and monomers: syntheses and structures;Dalton Transactions;2024
2. Molecular Weight Determination of Relevant Organometallic Catalysts in Solution by DOSY-NMR to Monitor Reactivity;Organometallics;2023-09-26
3. Sodiated Oppolzer enolates: solution structures, mechanism of alkylation, and origin of stereoselectivity;Organic Chemistry Frontiers;2023
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