Substitution Reactions at a Bridging Silicon Ligand. Formation of a Bis(μ-silylene) Complex Containing a Trifluoroacetoxy Group. Mechanistic Studies of the Site-Exchange Process of the Hydride Ligands-Reference-Cited by-同舟云学术

Substitution Reactions at a Bridging Silicon Ligand. Formation of a Bis(μ-silylene) Complex Containing a Trifluoroacetoxy Group. Mechanistic Studies of the Site-Exchange Process of the Hydride Ligands

Published:2005-01-13 Issue:4 Volume:24 Page:521-532
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Takao Toshiro¹,Yoshida Shigeru¹,Suzuki Hiroharu¹

Affiliation:

1. Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-Ku, Tokyo 152-8552, Japan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om049328h

Reference58 articles.

1. Synthesis, Characterization, and Reactivities of Diruthenium Complexes Containing a .mu.-Silane Ligand and Structural Studies of the .mu.-Silane Complex [Cp'Ru(CO)]2(.mu.-.eta.2:.eta.2-H2SitBu2)

2. Reactions of Diruthenium Tetrahydride Complex (η5-C5Me5)Ru(μ-H)4Ru(η5-C5Me5) with Vinylsilanes: Formation of a μ-Silylene Complex via Successive Si−H and Si−C Bond Cleavage of Dimethylvinylsilane

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