Iridium-catalyzed selective 1,2-hydrosilylation of N-heterocycles
Author:
Affiliation:
1. Department of Chemistry
2. Korea Advanced Institute of Science & Technology (KAIST)
3. Daejeon 305-701
4. South Korea
5. Center for Catalytic Hydrocarbon Functionalizations
Abstract
A silylene-bridged Ir dimer in situ generated from [Ir(coe)2Cl]2 and Et2SiH2 was found to catalyze the hydrosilylation of N-heteroaromatics to furnish dearomatized azacyclic products with high activity (up to 1000 TONs), excellent selectivity, and good functional group tolerance.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC01037G
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