Regioselective Addition of tert-BuN⋮C to the α Carbon Atom of the Allenyl Ligand in [Fe2(CO)6(μ-PPh2){μ-η1:η2α,β-(H)CαCβCγH2}]: Formation of [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuN⋮C)CCCH3}] and [Fe2(CO)6(μ-PPh2)(μ-η1:η2-{tert-BuNHC(O)CH2}CCH2)] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)HCCCH2}]-Reference-Cited by-同舟云学术

Regioselective Addition of tert-BuN⋮C to the α Carbon Atom of the Allenyl Ligand in [Fe2(CO)6(μ-PPh2){μ-η1:η2α,β-(H)CαCβCγH2}]: Formation of [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuN⋮C)CCCH3}] and [Fe2(CO)6(μ-PPh2)(μ-η1:η2-{tert-BuNHC(O)CH2}CCH2)] via Competitive 1,3-Hydrogen Migration and Hydrolysis of the Reactive Allene-Bridged Intermediate [Fe2(CO)6(μ-PPh2){μ-η1:η1-(tert-BuNC)HCCCH2}]

Published:1999-07-10 Issue:16 Volume:18 Page:3178-3186
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Doherty Simon¹,Hogarth Graeme¹,Waugh Mark¹,Scanlan Tom H.¹,Clegg William¹,Elsegood Mark R. J.¹

Affiliation:

1. Department of Chemistry, Bedson Building, The University of Newcastle upon Tyne, Newcastle upon Tyne, NE1 7RU, U.K., and Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, U.K.

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9901630

Reference54 articles.

1. Homometallic and Heterometallic Transition Metal Allenyl Complexes: Synthesis, Structure, and Reactivity

2. Reactivity patterns for .mu.-.eta.1:.eta.2-allenyl complexes. A novel synthetic route to dimetallacyclopentanes and dimetallacyclopentenes via regiospecific additions of carbon, nitrogen, and phosphorus nucleophiles to Ru2(CO)6(.mu.-.eta.1:.eta.2-PhC:C:CH2)(.mu.-PPh2)

3. An unprecedented regiospecific attack of phosphorus nucleophiles at Cαof the allenyl ligand in [Fe2(CO)6(µ-PPh2){µ-η1: η2α,β-(H)CαCβCγH2}]

4. Kinetic Addition of Nucleophiles to η3-Propargyl Rhenium Complexes Occurs at the Central Carbon to Produce Rhenacyclobutenes

5. Nucleophilic attack at the central carbon of a cationic (.eta.3-propargyl)rhenium complex

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