Crystal structure oftert-butyl-N-phenylcarbonitrilium tetrachloridoaluminate-Reference-Cited by-同舟云学术

Crystal structure oftert-butyl-N-phenylcarbonitrilium tetrachloridoaluminate

Published:2014-10-11 Issue:11 Volume:70 Page:331-333
ISSN:1600-5368
Container-title:Acta Crystallographica Section E Structure Reports Online
language:
Short-container-title:Acta Cryst E

Author:

Dijk Tom van,Zant Dirk W.,Wolf Robert,Lammertsma Koop,Slootweg J. Chris

Abstract

In the title compound, (C11H14N)[AlCl4], the nitrilium (systematic name: 2,2-dimethyl-N-phenylpropanenitrilium) ion adopts a slightly distorted linear configuration [C—N[triple-bond]C = 178.87 (16) and N[triple-bond]C—C = 179.13 (17)°]. In the crystal, while there are no intermolecular hydrogen bonds, pairs of nitrilium ions are linked through π–π interactions [inter–centroid distance = 3.8091 (13) Å].

Publisher

International Union of Crystallography (IUCr)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

Link

http://journals.iucr.org/e/issues/2014/11/00/kj2242/kj2242.pdf

Reference20 articles.

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