Organometallic Enantiomeric Scaffolding. Sequential Semipinacol/1,5-“Michael-like” Reactions as a Strategic Approach to Bridgehead-Quaternary Center Aza[3.3.1]Bicyclics: Application to the Total Synthesis of (−)-Adaline-Reference-Cited by-同舟云学术

Organometallic Enantiomeric Scaffolding. Sequential Semipinacol/1,5-“Michael-like” Reactions as a Strategic Approach to Bridgehead-Quaternary Center Aza[3.3.1]Bicyclics: Application to the Total Synthesis of (−)-Adaline

Published:2009-01-05 Issue:3 Volume:131 Page:876-877
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Coombs Thomas C.¹,Zhang Yongqiang¹,Garnier-Amblard Ethel C.¹,Liebeskind Lanny S.¹

Affiliation:

1. Sanford S. Atwood Chemistry Center, Emory University, 1515 Dickey Drive, Atlanta, Georgia 30322;

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja808533z

Reference37 articles.

1. Enantiocontrolled Synthesis of 2,6-Disubstituted Piperidines by Desymmetrization of meso-η-(3,4,5)-Dihydropyridinylmolybdenum Complexes. Application to the Total Synthesis of (−)-Dihydropinidine and (−)-Andrachcinidine

2. η3-Pyranyl and η3-Pyridinyl Molybdenum π-Complexes as Chiral Scaffolds for the Enantioselective Construction of Substituted Oxa- and Aza[3.3.1]bicyclics: First Enantio- and Regiocontrolled [5+3] Cycloaddition Reactions

3. New Oxidative Demetalation Protocol for Molybdenum π-Complexes: Enantiocontrolled Synthesis of Unsaturated Ketones and Lactones

4. Enantiocontrolled Synthesis of 2,3,6-Trisubstituted Piperidines Using (η3-Dihydropyridinyl)molybdenum Complexes as Chiral Scaffolds. Total Synthesis of (−)-Indolizidine 209B

5. Chiral Scaffolds for Enantiocontrolled Synthesis: Enantio- and Regiocontrolled [4 + 2] Cycloaddition to 3-Alkenyl-η3-Pyranylmolybdenum Complexes

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