Gas-Phase Synthesis of Charged Copper and Silver Fischer Carbenes from Diazomalonates:  Mechanistic and Conformational Considerations in Metal-Mediated Wolff Rearrangements

Author:

Julian Ryan R.1,May Jeremy A.1,Stoltz Brian M.1,Beauchamp J. L.1

Affiliation:

1. Contribution from the Beckman Institute and The Arnold and Mabel Beckman Laboratories of Chemical Synthesis, Division of Chemistry and Chemical Engineering, California Institute of Technology, Pasadena, California 91125

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference28 articles.

1. Mechanistic Studies of Olefin Metathesis by Ruthenium Carbene Complexes Using Electrospray Ionization Tandem Mass Spectrometry

2. Mass Spectrometric Detection of Reactive Intermediates. Reaction Mechanism of Diazoalkanes with Platinum(0) and Gold(I) Complexes

3. Doyle, M. P.; McKervey, M. A.; Ye, T.Modern Catalytic Methods for OrganicSynthesis with Diazo Compounds; Wiley-Interscience:  New York, 1998. (b) Moody, C. J.; Whitham, G. H.Reactive Intermediates; Oxford University Press:  New York, 1992; pp 26−50. (c) Straub, B. F.; Hofmann, P.Angew.Chem.Int. Ed.2001,40, 1288−1290.

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