Facile Conversion of Bis-Silylene to Cyclic Silylene Isomers: Unexpected C–N and C–H Bond Cleavage

Author:

Wang Yuzhong1ORCID,Hickox Hunter P.1,Xie Yaoming1,Wei Pingrong1,Schaefer Henry F.1ORCID,Robinson Gregory H.1ORCID

Affiliation:

1. Department of Chemistry and the Center for Computational Chemistry, The University of Georgia, Athens, Georgia 30602-2556, United States

Funder

Division of Chemistry

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Reference58 articles.

1. Dimethylsilene: CH3SiCH3

2. Divalent Silicon Intermediates

3. Gaspar, P. P.; West, R.InThe Chemistry of Organic Silicon Compounds;Rappaport, Z.; Apeloig, Y., Eds.John Wiley & Sons:Chichester, 1998; Vol.2, Part 3, pp2463–2567.

4. Koecher, T.; Kerst, C.; Friedrichs, G.; Temps, F.InSilicon Chemistry;Jutzi, P.; Schubert, U., Eds.Wiley-VCH:Weinheim, 2003; p44–57.

5. Hyperfine Interactions in HSiCl

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