Synthesis, Structural Characterization and Coordination Chemistry of a NHC‐stabilized Iminoborane-Reference-Cited by-同舟云学术

Synthesis, Structural Characterization and Coordination Chemistry of a NHC‐stabilized Iminoborane

Published:2023-07-03 Issue:15 Volume:18 Page:
ISSN:1861-4728
Container-title:Chemistry – An Asian Journal
language:en
Short-container-title:Chemistry An Asian Journal

Author:

Yue Xin¹,Wu Linlin²,Wang Hao¹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering Southeast University Nanjing 211189 P. R. China

2. Hunan Provincial Key Laboratory of Micro & Nano Materials Interfaces Science College of Chemistry and Chemical Engineering Central South University Changsha 410083 P. R. China

Abstract

AbstractNHC‐stabilized iminoborane4was prepared and structurally characterized via the reduction of a cationic iminoborane with potassium graphite. Compound4could be served as a supporting ligand for the synthesis of both main group and transition metal complexes through variable coordination modes. This study demonstrates the rich coordination chemistry of the Lewis base‐stabilized iminoborane.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Wiley

Subject

General Chemistry,Biochemistry,Organic Chemistry

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/asia.202300411

Reference64 articles.

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3. Verschiedene Reaktivitäten von Iminoboranen gegenüber Carbenen: BN-Isostere von Carben-Alkin-Addukten

4. Unraveling the reactivity of a cationic iminoborane: avenues to unusual boron cations

5. New Approaches to N-Heterocyclic-Carbene-Coordinated Iminoborane and Borenium Species