Boron-Promoted Deprotonative Conjugate Addition: Geminal Diborons as Soft Pronucleophiles and Acyl Anion Equivalents
Author:
Affiliation:
1. Department of Chemistry and Chemical Biology, Stevens Institute of Technology, Hoboken, New Jersey 07030, United States
Funder
Stevens Institute of Technology
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.2c00914
Reference52 articles.
1. gem-Diborylalkanes: recent advances in their preparation, transformation and application
2. Geminal bis(boron) compounds: Their preparation and synthetic applications
3. Synthesis and Reactivity of 1,1-Diborylalkanes towards C-C Bond Formation and Related Mechanisms
4. Development of Transition-Metal-Free Carbon-Carbon and Carbon-Boron Bond-Forming Reactions by Utilizing 1,1-Bis[(Pinacolato)Boryl]Alkanes
5. Deprotonation of 1,1-diboronic esters and reactions of the carbanions with alkyl halides and carbonyl compounds
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3. Synthesis of Quaternary and Tertiary Carbon‐Substituted Arenes by Lewis Base Promoted Site‐Selective Coupling with Allylic Nucleophiles;Angewandte Chemie International Edition;2023-07-11
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