I2–DMSO–H2O: A Metal-Free Combination System for the Oxidative Addition of Alkynes to Access (E)-α-Iodo-β-methylsulfonylalkenes
Author:
Affiliation:
1. College of Chemistry, Guangdong University of Petrochemical Technology, 2 Guandu Road, Maoming 525000, P. R. China
2. Shenzhen Grubbs Institute, Southern University of Science and Technology (SUSTech), Shenzhen 518055, P. R. China
Funder
Guangdong Science and Technology Department
National Natural Science Foundation of China
Natural Science Foundation of Guangdong Province
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.joc.9b02302
Reference29 articles.
1. Direct difunctionalization of activated alkynes via domino oxidative benzylation/1,4-aryl migration/decarboxylation reactions under metal-free conditions
2. Copper Nitrate Mediated Regio- and Stereoselective Difunctionalization of Alkynes: A Direct Approach to α-Chloro-β-nitroolefins
3. Direct vicinal difunctionalization of alkynes through trifluoromethylation and aminosulfonylation via insertion of sulfur dioxide under catalyst-free conditions
4. Copper-Catalyzed Radical Reaction of N-Tosylhydrazones: Stereoselective Synthesis of (E)-Vinyl Sulfones
5. Synthesis of (E)-β-iodo vinylsulfones via iodine-promoted iodosulfonylation of alkynes with sodium sulfinates in an aqueous medium at room temperature
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