Enhanced Reactivity in Hydrogen Atom Transfer from Tertiary Sites of Cyclohexanes and Decalins via Strain Release: Equatorial C–H Activation vs Axial C

Enhanced Reactivity in Hydrogen Atom Transfer from Tertiary Sites of Cyclohexanes and Decalins via Strain Release: Equatorial C–H Activation vs Axial C–H Deactivation

Published:2015-04-14 Issue:9 Volume:80 Page:4710-4715
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Salamone Michela¹,Ortega Vanesa B.¹,Bietti Massimo¹

Affiliation:

1. Dipartimento di Scienze e Tecnologie Chimiche, Università “Tor Vergata”, Via della Ricerca Scientifica, 1 I-00133 Rome, Italy

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/acs.joc.5b00636

Reference40 articles.

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3. Adding Aliphatic C–H Bond Oxidations to Synthesis

4. A Predictably Selective Aliphatic C–H Oxidation Reaction for Complex Molecule Synthesis

5. Innate and Guided C–H Functionalization Logic

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