Bi(cyclopentyl)diol-Derived Boronates in Highly Enantioselective Chiral Phosphoric Acid-Catalyzed Allylation, Propargylation, and Crotylation of Aldehydes

Author:

Yuan Jinping1,Jain Pankaj2,Antilla Jon C.13

Affiliation:

1. Institute for Molecular Design and Synthesis, School of Pharmaceutical Science and Technology, Tianjin University, Tianjin 300072, China

2. Novartis Institutes for BioMedical Research, Cambridge, Massachusetts 02139, United States

3. School of Sciences, Zhejiang Sci-Tech University, Hangzhou City, Zhejiang Province 310018, China

Funder

Tianjin University

Central Committee of the Communist Party of China

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Reference93 articles.

1. aRoush, W. R. Comprehensive Organic Synthesis; Trost, B. M., Ed. Pergamon Press: Oxford, U.K., 1991; Vol. 2, pp 1–54.

2. bLachance, H.; Hall, D. G. In Organic Reactions; Denmark, S. E., Ed. John Wiley & Sons, Inc., 2008; Vol. 73, pp 1–69.

3. cDenmark, S. E.; Almstead, N. G. In Modern Carbonyl Chemistry; Otera, J., Ed. Wiley-VCH: Weinheim, 2000; Chapter 10, pp 299–402.

4. dChemler, S. R.; Roush, W. R. In Modern Carbonyl Chemistry; Otera, J., Ed. Wiley-VCH: Weinheim, 2000; Chapter 11, pp 403–490.

5. Chiral synthesis via organoboranes. 35. Simple procedures for the efficient recycling of the terpenyl chiral auxiliaries and convenient isolation of the homoallylic alcohols in asymmetric allyl- and crotylboration of aldehydes

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