Influence of Filled dπ-Manifold and L/L‘ Ligands on the Structure, Basicity, and Bond Rotations of the Octahedral and d6 Amido Complexes TpRu(L)(L‘)(NHPh) (Tp = Hydridotris(pyrazolyl)borate; L = L‘ = PMe3 or P(OMe)3, or L = CO and L‘ = PPh3): Solid-State Structures of [TpRu(PMe3)2(NH2Ph)][OTf], [TpRu{P(OMe)3}2(NH2Ph)][OTf], and TpRu{P(OMe)3}2(NHPh)
Author:
Affiliation:
1. Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic020163j
Reference39 articles.
1. Homogeneously catalyzed amination of alkenes
2. Transition metal and enzyme catalyzed reactions involving reactions with ammonia and amines
3. Relative metal-hydrogen, -oxygen, -nitrogen, and -carbon bond strengths for organoruthenium and organoplatinum compounds; equilibrium studies of Cp*(PMe3)2RuX and (DPPE)MePtX systems
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