Insights into metal–ligand hydrogen transfer: a square-planar ruthenate complex supported by a tetradentate amino–amido-diolefin ligand

Author:

Prokopchuk Demyan E.12345,Lough Alan J.1234,Rodriguez-Lugo Rafael E.5678,Morris Robert H.1234,Grützmacher Hansjörg5678

Affiliation:

1. Department of Chemistry

2. University of Toronto

3. Toronto

4. Canada

5. Department of Chemistry and Applied Biosciences

6. ETH Zürich

7. 8093 Zürich

8. Switzerland

Abstract

A unique square planar anionic ruthenium(0) complex with amido and amine donors undergoes rapid NH oxidative addition/elimination reactions.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference50 articles.

1. J. Harmer , G.Frison, M.Rudolph, H.Schönberg, S.Deblon, P.Maire, S.Boulmaaz, F.Breher, C.Bohler, H.Ruegger, A.Schweiger and H.Grützmacher, Perspectives in Organometallic Chemistry, The Royal Society of Chemistry, 2003, pp. 222

2. Chiral Olefins as Steering Ligands in Asymmetric Catalysis

3. A Monomeric d9-Rhodium(0) Complex

4. Amine olefin rhodium(i) complexes: pKaand NH bond strength

5. Heterolytic Splitting of Hydrogen with Rhodium(I) Amides

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