W(CO)5-Amine Catalyzed Exo- and Endo-Selective Cyclizations of ω-Alkynyl Silyl Enol Ethers: A Highly Useful Method for the Construction of Polycyclic Compounds-Reference-Cited by-同舟云学术

W(CO)5-Amine Catalyzed Exo- and Endo-Selective Cyclizations of ω-Alkynyl Silyl Enol Ethers: A Highly Useful Method for the Construction of Polycyclic Compounds

Published:2002-06-26 Issue:15 Volume:4 Page:2569-2571
ISSN:1523-7060
Container-title:Organic Letters
language:en
Short-container-title:Org. Lett.

Author:

Kusama Hiroyuki¹,Yamabe Hokuto¹,Iwasawa Nobuharu¹

Affiliation:

1. Department of Chemistry, Tokyo Institute of Technology, O-okayama, Meguro-ku, Tokyo 152-8551, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ol026202c

Reference7 articles.

1. Reactions of complex ligands. 29. Metal-assisted cyclization of alkynols at a d6 metal template. One-pot synthesis of 2-oxacycloalkylidene complexes of chromium, tungsten, and manganese

2. A Novel Reaction for Annulation onto α,β-Unsaturated Ketones: W(CO)5·L Promoted Exo- and Endo-Selective Cyclizations of ω-Acetylenic Silyl Enol Ethers Prepared by 1,4-Addition of Propargyl Malonate to Enones

3. W(CO)5·THF-Catalyzed Endo-Selective Cyclization of ω-Acetylenic Silyl Enol Ethers

4. Generation and Reaction of Metal-Containing Carbonyl Ylides: Tandem [3+2]-Cycloaddition−Carbene Insertion Leading to Novel Polycyclic Compounds

5. Reactions of Iodinated Vinylidene Complexes Generated from 1-Iodo-1-alkynes and W(CO)5(thf)

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