Arylruthenium(III) Porphyrin-Catalyzed C–H Oxidation and Epoxidation at Room Temperature and [RuV(Por)(O)(Ph)] Intermediate by Spectroscopic Analysis and Density Functional Theory Calculations-Reference-Cited by-同舟云学术

Arylruthenium(III) Porphyrin-Catalyzed C–H Oxidation and Epoxidation at Room Temperature and [RuV(Por)(O)(Ph)] Intermediate by Spectroscopic Analysis and Density Functional Theory Calculations

Published:2018-05-21 Issue:22 Volume:140 Page:7032-7042
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Shing Ka-Pan¹,Cao Bei¹,Liu Yungen¹,Lee Hung Kay²,Li Ming-De¹,Phillips David Lee¹^ORCID,Chang Xiao-Yong¹^ORCID,Che Chi-Ming¹³^ORCID

Affiliation:

1. Department of Chemistry and State Key Laboratory of Synthetic Chemistry, The University of Hong Kong, Pokfulam Road, Hong Kong, China

2. Department of Chemistry, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong, China

3. HKU Shenzhen Institute of Research and Innovation, Shenzhen 518053, China

Funder

Research Grants Council, University Grants Committee

Ministry of Science and Technology of the People's Republic of China

Shenzhen Municipality

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/jacs.8b04470

Reference90 articles.

1. Metalloporphyrins as versatile catalysts for oxidation reactions and oxidative DNA cleavage

2. bGroves, J. T. Cytochrome P450: Structure, Mechanism, and Biochemistry; Ortiz de Montellano, P. R., Ed. Kluwer Academic/Plenum Publishers: New York, 2005, 3rd ed., p 1.

3. High-Valent Iron(IV)–Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions

4. Hydroxylation and epoxidation catalyzed by iron-porphine complexes. Oxygen transfer from iodosylbenzene

5. Reaction of iron(III) porphyrins and iodosoxylene. The active oxene complex of cytochrome P-450

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