Water co-catalysis in aerobic olefin epoxidation mediated by ruthenium oxo complexes-Reference-Cited by-同舟云学术

Water co-catalysis in aerobic olefin epoxidation mediated by ruthenium oxo complexes

Published:2024 Issue:9 Volume:15 Page:3104-3115
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Cao Qun¹²^ORCID,Diefenbach Martin³^ORCID,Maguire Calum¹^ORCID,Krewald Vera³^ORCID,Muldoon Mark J.¹^ORCID,Hintermair Ulrich²^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Queen's University Belfast, Northern Ireland, UK

2. Dynamic Reaction Monitoring Facility, Institute for Sustainability, University of Bath, UK

3. Theoretical Chemistry, Department of Chemistry, Technische Universität Darmstadt, Germany

Abstract

A versatile Ru-porphyrin catalyst system was developed for the mild and selective aerobic epoxidation of alkenes in which water was shown to play a key role as corroborated by detailed mechanistic studies.

Funder

Royal Society

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D3SC05516G

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