Unlocking Structural Diversity in Gold(III) Hydrides: Unexpected Interplay of cis/trans-Influence on Stability, Insertion Chemistry, and NMR Chemical Shifts-Reference-Cited by-同舟云学术

Unlocking Structural Diversity in Gold(III) Hydrides: Unexpected Interplay of cis/trans-Influence on Stability, Insertion Chemistry, and NMR Chemical Shifts

Published:2018-06-04 Issue:26 Volume:140 Page:8287-8302
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Rocchigiani Luca¹^ORCID,Fernandez-Cestau Julio¹^ORCID,Chambrier Isabelle¹^ORCID,Hrobárik Peter²³^ORCID,Bochmann Manfred¹^ORCID

Affiliation:

1. School of Chemistry, University of East Anglia, Norwich Research Park, NR4 7TJ Norwich, United Kingdom

2. Institut für Chemie, Technische Universität Berlin, Straße des 17. Juni 135, D-10623 Berlin, Germany

3. Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University, SK-84215 Bratislava, Slovakia

Funder

Vedeck? Grantov? Agent?ra M?VVa? SR a SAV

Deutsche Forschungsgemeinschaft

H2020 Marie Sklodowska-Curie Actions

FP7 Ideas: European Research Council

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

http://pubs.acs.org/doi/pdf/10.1021/jacs.8b04478

Reference56 articles.

1. Introduction: Metal Hydrides

2. Introduction: Metal Hydrides

3. The gold–hydrogen bond, Au–H, and the hydrogen bond to gold, Au⋯H–X

4. Gold Hydrides AuH and (H2)AuH and the AuH3 Transition State Stabilized in (H2)AuH3: Infrared Spectra and DFT Calculations

5. Gold Is Noble but Gold Hydride Anions Are Stable

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