One-Pot Synthesis for Osmium(II) Azavinylidene−Carbyne and Azavinylidene−Alkenylcarbyne Complexes Starting from an Osmium(II) Hydride−Azavinylidene Compound-Reference-Cited by-同舟云学术

One-Pot Synthesis for Osmium(II) Azavinylidene−Carbyne and Azavinylidene−Alkenylcarbyne Complexes Starting from an Osmium(II) Hydride−Azavinylidene Compound

Published:2001-06-15 Issue:15 Volume:20 Page:3283-3292
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Castarlenas Ricardo¹,Esteruelas Miguel A.¹,Oñate Enrique¹

Affiliation:

1. Departamento de Química Inorgánica-Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om0101386

Reference66 articles.

1. Synthesis of new hydride-carbyne and hydride-vinylcarbyne complexes of osmium(II) by reaction of OsH2Cl2(P-iso-Pr3)2 with terminal alkynes

2. Reactions of the Dihydrogen Complex OsCl2(.eta.2-H2)(CO)(PiPr3)2 with Terminal Alkynes: Synthesis of Carbene, Vinylcarbene, and .mu.-Bis-carbene Osmium (II) Derivatives

3. Seven-Coordinate Dihydrido Complex OsH2(κ2-O2CCH3){κ1-OC(O)CH3}(PiPr3)2 as Precursor of New Organometallic Compounds Containing Unsaturated η1-Carbon Ligands

4. Reactions of New Osmium−Dihydride Complexes with Terminal Alkynes: Metallacyclopropene versus Metal−Carbyne. Influence of the Alkyne Substituent

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