Seven-Coordinate Dihydrido Complex OsH2(κ2-O2CCH3){κ1-OC(O)CH3}(PiPr3)2 as Precursor of New Organometallic Compounds Containing Unsaturated η1-Carbon Ligands-Reference-Cited by-同舟云学术

Seven-Coordinate Dihydrido Complex OsH2(κ2-O2CCH3){κ1-OC(O)CH3}(PiPr3)2 as Precursor of New Organometallic Compounds Containing Unsaturated η1-Carbon Ligands

Published:1998-09-01 Issue:20 Volume:17 Page:4500-4509
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Crochet Pascale¹,Esteruelas Miguel A.¹,López Ana M.¹,Martínez María-Pilar¹,Oliván Montserrat¹,Oñate Enrique¹,Ruiz Natividad¹

Affiliation:

1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-Consejo Superior de Investigaciones Científicas, 50009 Zaragoza, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om9803366

Reference56 articles.

1. Synthesis, reactivity, molecular structure, and catalytic activity of the novel dichlorodihydridoosmium(IV) complexes OsH2Cl2(PR3)2 (PR3 = P-i-Pr3, PMe-t-Bu2)

2. Structural and Dynamic Properties of OsH2X2L2 (X = Cl, Br, I; L = PiPr3) Complexes: Interconversion between Remarkable Non-Octahedral Isomers

3. An unusual example of hydrogen molecule (H2) coordination by a d4 metal center: reactions between OsH2Cl2(PPr-iso3)2 and H2

4. Distinct structures for ruthenium and osmium hydrido halides: Os(H)3X(PiPr3)2 (X = Cl, Br, I) are nonoctahedral classical trihydrides with exchange coupling

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