Dramatic Improvement of the Enantiomeric Excess in the Asymmetric Conjugate Addition Reaction Using New Experimental Conditions
Author:
Affiliation:
1. Department of Organic Chemistry, University of Geneva, 30, Quai Ernest Ansermet, 1211 Geneva 2, Switzerland
Publisher
American Chemical Society (ACS)
Subject
Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis
Link
https://pubs.acs.org/doi/pdf/10.1021/ja025598k
Reference21 articles.
1. Krause, N.; Hoffmann-Röder, A.Synthesis2001, 171. Sibi, M. P.; Manyem, S.Tetrahedron2000,56, 8033.Alexakis in Transition MetalCatalysed Reaction; Murahashi, S.I., Davies, S. G., Eds.; IUPAC Blackwell Science: Oxford, 1999; p 303.
2. (a) Alexakis, A.; Frutos, J.; Mangeney, P.Tetrahedron: Asymmetry1993,4, 2427.
3. Acceleration of the conjugate addition of diethyl zinc to enones by either Cu(OTf)2 or trivalent phosphorus ligands
4. Methylene-Bridged P-Chiral Diphosphines in Highly Enantioselective Reactions
5. Enantioselective copper-catalyzed conjugate addition of diethylzinc to enones using new chiral P,N ligands composed of (S)-2-alkyl-2-aminoethylphosphines and α-substituted pyridines
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