Unsymmetrically Substituted 1,1′-Biferrocenylenes Maintain Class III Mixed-Valence Character
Author:
Affiliation:
1. Center of Micro- and Nanochemistry and Engineering, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Straße 2, D-57068 Siegen, Germany
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/om400502e
Reference107 articles.
1. Organic Mixed-Valence Compounds: A Playground for Electrons and Holes
2. Organic Mixed Valence
3. Electron Transfer Studies on Ferrocenylthiophenes: Synthesis, Properties, and Electrochemistry
4. Optical transitions of symmetrical mixed-valence systems in the Class II–III transition regimeElectronic supplementary information (ESI) is available: derivation of eqn. (39c), table summarizing the relationships between band maxima and band widths predicted by the two-state model and table of spectral properties of mixed-valence ruthenium(II)/(III) bridged by pyrazine and dicyanamide. See http://www.rsc.org/suppdata/cs/b0/b008034i/
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