Unimolecular HCl and HF Elimination Reactions of 1,2-Dichloroethane, 1,2-Difluoroethane, and 1,2-Chlorofluoroethane: Assignment of Threshold Energies
Author:
Affiliation:
1. Department of Chemistry, University of North Carolina at Asheville, One University Heights, Asheville, North Carolina 28804-8511, and Department of Chemistry, Kansas State University, Manhattan, Kansas 66506
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jp908483m
Reference58 articles.
1. Vibrational energy transfer probabilities of highly vibrationally excited fluoroethane and 1,2-difluoroethane molecules
2. Unimolecular Reaction and Collisional Deactivation of Chemically Activated 1,2-Difluoroethane Produced by Mercury Photosensitization of Chlorofluoromethane at 300 and 475°K
3. Application of the RRKM theory to the unimolecular decomposition of 1,2-difluoroethane
4. A kinetic study of the thermal elimination of hydrogen fluoride from 1,2-difluoroethane. Determination of the bond dissociation energiesD(CH2F?CH2F) andD(CH2F?H).
5. Photochemistry of the Fluoro Ketones. The Production of Vinyl Fluoride in the Photolysis of 1,3-Difluoroacetone1
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3. Experimental and Computational Studies of Unimolecular 1,1-HX (X = F, Cl) Elimination Reactions of C2D5CHFCl: Role of Carbene:HF and HCl Adducts in the Exit Channel of RCHFCl and RCHCl2 Reactions;The Journal of Physical Chemistry A;2019-03-06
4. Analysis of the Five Unimolecular Reaction Pathways of CD2ClCHFCl with Emphasis on CD2Cl(F)C: and CD2Cl(Cl)C: Formed by 1,1-HCl and 1,1-HF Elimination;The Journal of Physical Chemistry A;2018-09-28
5. The Unimolecular Reactions of CF3CHF2 Studied by Chemical Activation: Assignment of Rate Constants and Threshold Energies to the 1,2-H Atom Transfer, 1,1-HF and 1,2-HF Elimination Reactions, and the Dependence of Threshold Energies on the Number of F-Atom Substituents in the Fluoroethane Molecules;The Journal of Physical Chemistry A;2017-11-09
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