The Unimolecular Reactions of CF3CHF2 Studied by Chemical Activation: Assignment of Rate Constants and Threshold Energies to the 1,2-H Atom Transfer, 1,1-HF and 1,2-HF Elimination Reactions, and the Dependence of Threshold Energies on the Number of F-Atom Substituents in the Fluoroethane Molecules
Author:
Affiliation:
1. Kansas State University, Manhattan, Kansas 66506, United States
Funder
Division of Chemistry
Publisher
American Chemical Society (ACS)
Subject
Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.jpca.7b06769
Reference52 articles.
1. Kinetics of the thermal decomposition of ethyl fluoride
2. 1970, 2498–2503.
3. A kinetic study of the thermal elimination of hydrogen fluoride from 1,2-difluoroethane. Determination of the bond dissociation energiesD(CH2F?CH2F) andD(CH2F?H).
4. Kinetics of the thermal decomposition of 1,1-difluoroethane in shock waves. Consecutive first-order reaction
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