An Efficient Synthesis of Dinitrile Derivatives by the Reaction of Oxime Esters or Acid Anhydrides with Cyanotrimethylsilane Catalyzed by La(OiPr)3
Author:
Affiliation:
1. Department of Applied Chemistry, Faculty of Engineering & High Technology, Research Center, Kansai University, Suita, Osaka 564-8680, Japan
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/jo0055281
Reference28 articles.
1. (a) March, J.Advanced Organic Chemistry, 4th ed.; Wiley: New York, 1992; pp 964−965.
2. Synthetic Applications of Cyanotrimethylsilane, lodotrimethylsilane, Azidotrimethylsilane, and Methylthiotrimethylsilane
3. Yb(CN)3-catalyzed reaction of aziridines with cyanotrimethylsilane. A facile synthesis of optically pure β-amino nitriles
4. Synthetic methods and reactions. 144. Regiospecific and chemoselective ring opening of epoxides with trimethylsilyl cyanide-potassium cyanide/18-crown-6 complex
5. Reaction of cyanotrimethylsilane with oxiranes. Effects of catalysts or mediators on regioselectivity and ambident character
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