Synthesis of (C5Me5)2(C5Me4H)UMe, (C5Me5)2(C5H5)UMe, and (C5Me5)2UMe[CH(SiMe3)2] from Cationic Metallocenes for the Evaluation of Sterically Induced Reduction
Author:
Affiliation:
1. Department of Chemistry, University of California, Irvine, California 92697-2025, and Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, MC 0358 La Jolla, California 92093-0358
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ic801232e
Reference52 articles.
1. Chemistry of Tris(pentamethylcyclopentadienyl) f-Element Complexes, (C5Me5)3M
2. C-H bond activation through steric crowding of normally inert ligands in the sterically crowded gadolinium and yttrium (C5Me5)3M complexes
3. Synthesis and Structure of a Thermally Stable, Nonclassical, 7-Norbornadienyl Carbocation Obtained from (C5Me5)3Sm and CO
4. Methyl Displacements from Cyclopentadienyl Ring Planes in Sterically Crowded (C5Me5)3M Complexes
5. Facile Triphenylborane-Based Syntheses of the Sterically Crowded Tris(pentamethylcyclopentadienyl) Complexes (C5Me5)3UMe and (C5Me5)3UCl
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