Divergent uranium- versus phosphorus-based reduction of Me3SiN3 with steric modification of phosphido ligands-Reference-Cited by-同舟云学术

Divergent uranium- versus phosphorus-based reduction of Me3SiN3 with steric modification of phosphido ligands

Published:2020 Issue:22 Volume:11 Page:5830-5835
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Ward Robert J.¹²³⁴,Rungthanaphatsophon Pokpong¹²³⁴,Rosal Iker del⁵⁶⁷⁸⁹,Kelley Steven P.¹²³⁴^ORCID,Maron Laurent⁵⁶⁷⁸⁹^ORCID,Walensky Justin R.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Missouri

3. Columbia

4. USA

5. Universite de Toulouse

6. CNRS

7. INSA

8. UPS

9. UMR

Abstract

We describe an example of a two-electron metal- and ligand-based reduction of Me₃SiN₃ using uranium(iv) complexes with varying steric properties. With uranium-based reduction, a U(vi) intermediate is isolated.

Funder

U.S. Department of Energy

Hydropower Foundation

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC02261F

Reference71 articles.

1. Cross-Coupling Reactions Of Organoboranes: An Easy Way To Construct CC Bonds (Nobel Lecture)