Synthesis and Redox Characterization of the Polyoxo Anion, γ*-[S2W18O62]4-: A Unique Fast Oxidation Pathway Determines the Characteristic Reversible Electrochemical Behavior of Polyoxometalate Anions in Acidic Media-Reference-Cited by-同舟云学术

Synthesis and Redox Characterization of the Polyoxo Anion, γ*-[S2W18O62]4-: A Unique Fast Oxidation Pathway Determines the Characteristic Reversible Electrochemical Behavior of Polyoxometalate Anions in Acidic Media

Published:2001-01-11 Issue:4 Volume:40 Page:703-709
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Richardt Peter J. S.¹,Gable Robert W.¹,Bond Alan M.¹,Wedd Anthony G.¹

Affiliation:

1. School of Chemistry, University of Melbourne, Parkville, Victoria 3052, Australia, and Department of Chemistry, Monash University, Clayton, Victoria 3168, Australia

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic000793q

Reference45 articles.

1. The structure of the 9(18)-heteropoly anion in potassium 9(18)-tungstophosphate, K6(P2W18O62).14H2O

2. Pope, M. T.Heteropoly and Isopoly Oxometalates; Springer-Verlag: Berlin, 1983; pp 69−70.

3. New fundamental type of inorganic complex: hybrid between heteropoly and conventional coordination complexes. Possibilities for geometrical isomerisms in 11-, 12-, 17-, and 18-heteropoly derivatives

4. A reinvestigation of isomerism in the Dawson structure: syntheses and 183W NMR structural characterization of three new polyoxotungstates [X2W18O62]6− (X=PV, AsV)

5. Multicomponent Polyanions. 12. The Crystal Structure of Na6Mo18P2O62(H2O)24, a Compound Containing Sodiumcoordinated 18-Molybdodiphoshate Anions.

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