Accelerated rates of proton coupled electron transfer to oxygen deficient polyoxovanadate–alkoxide clusters-Reference-Cited by-同舟云学术

Accelerated rates of proton coupled electron transfer to oxygen deficient polyoxovanadate–alkoxide clusters

Published:2023 Issue:9 Volume:10 Page:2754-2765
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Cooney Shannon E.¹^ORCID,Schreiber Eric¹^ORCID,Brennessel William W.¹^ORCID,Matson Ellen M.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Rochester, Rochester, NY 14627, USA

Abstract

The rate of O-atom defect formation on a reduced POV-alkoxide via PCET is accelerated despite weakened surface O–H bonds. Increased electron density and terminal VO basicity break classical driving force/rate scaling relationships.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI00129F

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1. Heterometal Dopant Changes the Mechanism of Proton-Coupled Electron Transfer at the Polyoxovanadate-Alkoxide Surface;Journal of the American Chemical Society;2024-01-19

2. Surface ligand length influences kinetics of H-atom uptake in polyoxovanadate-alkoxide clusters;Dalton Transactions;2023