Syntheses, Reactivity, and π-Donating Ligand Metathesis Reaction of Five-Coordinate Sixteen-Electron Manganese(I) Complexes: Crystal Structures of [Mn(CO)3(−TeC6H4-o-NH−)]-, [(Mn(CO)3)2(μ-SC6H4-o-S−S−C6H4-o-μ-S−)], [(CO)3Mn(μ-SC6H4-o-NH2−)]2, and [(CO)3Mn(μ-SC8N2H4-o-S−)]22--Reference-Cited by-同舟云学术

Syntheses, Reactivity, and π-Donating Ligand Metathesis Reaction of Five-Coordinate Sixteen-Electron Manganese(I) Complexes: Crystal Structures of [Mn(CO)3(−TeC6H4-o-NH−)]-, [(Mn(CO)3)2(μ-SC6H4-o-S−S−C6H4-o-μ-S−)], [(CO)3Mn(μ-SC6H4-o-NH2−)]2, and [(CO)3Mn(μ-SC8N2H4-o-S−)]22-

Published:2001-06-06 Issue:14 Volume:40 Page:3468-3475
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Liaw Wen-Feng¹,Hsieh Chien-Kuo¹,Lin Ging-Yi¹,Lee Gene-Hsiang¹

Affiliation:

1. Department of Chemistry, National Changhua University of Education, Changhua 50058, Taiwan, and Instrumentation Center, National Taiwan University, Taipei 10764, Taiwan

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic000795a

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3. A low-spin iron with CN and CO as intrinsic ligands forms the core of the active site in [Fe]-hydrogenases

4. Identification of A Putative Histidine Base and of a Non-Protein Nitrogen Ligand in the Active Site of Fe-Hydrogenases by One-Dimensional and Two-Dimensional Electron Spin-Echo Envelope-Modulation Spectroscopy

5. Electronic Structure of the H Cluster in [Fe]-Hydrogenases

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