Copper-Catalyzed γ-Selective and Stereospecific Allyl−Aryl Coupling between (Z)-Acyclic and Cyclic Allylic Phosphates and Arylboronates

Author:

Ohmiya Hirohisa1,Yokokawa Natsumi1,Sawamura Masaya1

Affiliation:

1. Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo 060-0810, Japan

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference26 articles.

1. Boronic Acids

2. Pd-catalyzed allyl−aryl couplings between allyl alcohol derivatives and arylboron compounds have been reported. These studies, however, have focused on cases in which an allylic system is located at the terminus of a molecule or is highly asymmetrized by electronic and/or steric substituent effects. See:

3. Novel and convenient method for the stereo- and regiospecific synthesis of conjugated alkadienes and alkenynes via the palladium-catalyzed cross-coupling reaction of 1-alkenylboranes with bromoalkenes and bromoalkynes

4. Palladium-catalyzed phenylation of allylic acetates by tetraphenylborate anion

5. Cross-Coupling of Aryl Halides and Allyl Acetates with Arylboron Reagents in Water Using an Amphiphilic Resin-Supported Palladium Catalyst

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