Axially Chiral Bichromophoric Fluorescent Dyes-Reference-Cited by-同舟云学术

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Axially Chiral Bichromophoric Fluorescent Dyes

Published:2011-01-13 Issue:3 Volume:76 Page:990-992
ISSN:0022-3263
Container-title:The Journal of Organic Chemistry
language:en
Short-container-title:J. Org. Chem.

Author:

Langhals Heinz¹,Hofer Alexander¹,Bernhard Stefan²,Siegel Jay S.³,Mayer Peter¹

Affiliation:

1. Department of Chemistry, LMU University of Munich, Butenandtstrasse 13, D-81377 Munich, Germany

2. Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, United States

3. Institute of Organic Chemistry, University of Zuerich, Winterthurerstrasse 190, CH-8057 Zurich, Switzerland

Publisher

American Chemical Society (ACS)

Subject

Organic Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/jo102254a

Reference25 articles.

1. THE ABSOLUTE CONFIGURATION OF 6,6'-DINITRO-2,2'-DIPHENIC ACID AND 6,6'-DIMETHYL-2,2'-BIPHENYLDIAMINE

2. The stereochemistry of the cyclopropane-allene conversion

3. Die absolute Konfiguration der atropisomeren Diaryl-Verbindungen

4. cThe author J.S.S. supports the technical aspects of this work fully but disagrees with the use of terminology like “axial chirality”; see:Mislow, K.; Siegel, J.J. Am. Chem. Soc. 1984, 106, 3319−3328.Cozzi, F.; Siegel, J. S.Org. Biomol. Chem. 2005, 3, 4296−4298. The author H.L. emphasizes that terms such as “axial chirality” or the “asymmetric carbon atom” are no more than useful chemical models for helical arrangements of electrons induced by the nuclear framework. Elements of symmetry of polyatomic molecules in solution are in no way verified in reality because of zero point vibrations and many other effects where, for example, phenomenologically achiral molecules form either fast equilibria of racemization or reach states with rotary alternating axes.

5. aBachrach, S. M. Computational Organic Chemistry;John Wiley & Sons:New York, 2007; pp394−395.

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