A “Push−Pull” Mechanism for Heterolytic O−O Bond Cleavage in Hydroperoxo Manganese Porphyrins

Author:

Jin Ning1,Lahaye Dorothée E.1,Groves John T.1

Affiliation:

1. Department of Chemistry, Princeton University, Princeton, New Jersey 08544, United States

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Reference78 articles.

1. P450 Enzymes: Their Structure, Reactivity, and Selectivity—Modeled by QM/MM Calculations

2. Groves, J. T.InCytochrome P450: Structure, Mechanism, and Biochemistry;3rded.Ortiz de Montellano, P. R., Ed.Kluwer Academic/Plenum:New York, 2005, p1−44.

3. Structure and Chemistry of Cytochrome P450

4. Mechanism of Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes

5. Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes

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