A Tandem Catalytic Approach to Methyleneindenes: Mechanistic Insights into gem-Dibromoolefin Reactivity
Author:
Affiliation:
1. Davenport Laboratories, Department of Chemistry, University of Toronto, Toronto, Ontario, Canada M5S 3H6
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/ol100844v
Reference54 articles.
1. A New Synthesis of 1,1-Dibromoölefins via Phosphine-Dibromomethylenes. the Reaction of Triphenylphosphine with Carbon Tetrabromide
2. A synthetic method for formyl→ethynyl conversion (RCHO→RCCH or RCCR′)
3. For a partial description of the catalytic reactions of dibromides, see:
4. Pd-Catalyzed Tandem C−N/C−C Coupling of gem-Dihalovinyl Systems: A Modular Synthesis of 2-Substituted Indoles
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