Palladium‐Catalyzed Bicyclization of 1‐(2,2‐Dibromovinyl)‐2‐Alkenylbenzene with Allenyl Malonates-Reference-Cited by-同舟云学术

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Palladium‐Catalyzed Bicyclization of 1‐(2,2‐Dibromovinyl)‐2‐Alkenylbenzene with Allenyl Malonates

Published:2024-09-05 Issue: Volume: Page:
ISSN:1615-4150
Container-title:Advanced Synthesis & Catalysis
language:en
Short-container-title:Adv Synth Catal

Author:

Zhou Ping‐Xin¹,Liu Yang¹,Wang Cui‐Tian²,Li Kexin¹,Ren Feng¹,Tan Xinqiang¹^ORCID,Liang Yong‐Min³^ORCID

Affiliation:

1. School of Basic Medical Sciences Xinxiang Medical University Xinxiang Henan 453003 People's Republic of China

2. School of Chemistry and Chemical Engineering Lanzhou Jiaotong University Anningxi Road 188 Lanzhou 730070 Gansu People's Republic of China

3. State Key Laboratory of Applied Organic Chemistry Lanzhou University Lanzhou 730000 People's Republic of China

Abstract

AbstractPalladium‐catalyzed bicyclization of 1‐(2,2‐dibromovinyl)‐2‐alkenylbenzene with allenyl malonates has been achieved to afford a series of bicyclic compounds. The protocol involves intermolecular carbopalladation of allenes/cyclization/internal Heck reaction. Three C−C bonds and two rings are formed in one step.

Publisher

Wiley

Link

https://onlinelibrary.wiley.com/doi/pdf/10.1002/adsc.202400415

Reference62 articles.

2. Transition Metal-Catalyzed/Mediated Reaction of Allenes with a Nucleophilic Functionality Connected to the α-Carbon Atom

3. Control of Selectivity in Palladium(II)-Catalyzed Oxidative Transformations of Allenes

4. Palladium-Catalyzed Cyclization Reactions of Allenes in the Presence of Unsaturated Carbon–Carbon Bonds

5. Some Typical Advances in the Synthetic Applications of Allenes

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