Synthesis and Spectroscopic Properties of Dihydrogen Isocyanide Niobocene [Nb(η5-C5H4SiMe3)2(η2-H2)(CNR)]+ Complexes. Experimental and Theoretical Study of the Blocked Rotation of a Coordinated Dihydrogen-Reference-Cited by-同舟云学术

Synthesis and Spectroscopic Properties of Dihydrogen Isocyanide Niobocene [Nb(η5-C5H4SiMe3)2(η2-H2)(CNR)]+ Complexes. Experimental and Theoretical Study of the Blocked Rotation of a Coordinated Dihydrogen

Published:1997-07-01 Issue:26 Volume:119 Page:6107-6114
ISSN:0002-7863
Container-title:Journal of the American Chemical Society
language:en
Short-container-title:J. Am. Chem. Soc.

Author:

Antiñolo Antonio¹,Carrillo-Hermosilla Fernando¹,Fajardo Mariano¹,Garcia-Yuste Santiago¹,Otero Antonio¹,Camanyes Santiago¹,Maseras Feliu¹,Moreno Miquel¹,Lledós Agustí¹,Lluch José M.¹

Affiliation:

1. Contribution from the Departamento de Química Inorgánica y Bioquímica, Universidad de Castilla-La Mancha, Campus Universitario de Ciudad Real, 13071 Ciudad Real, Spain, Departamento de Química Inorgánica, Universidad de Alcalá, 28871 Alcalá de Henares, Spain, Departament de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Barcelona, Spain, and Laboratoire de Structure et Dynamique des Systèmes Moleculaires et Solides, U.M.R. 5636, Université de Montpellier II, 34095 Montpellier Cedex 5, France

Publisher

American Chemical Society (ACS)

Subject

Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis

Link

https://pubs.acs.org/doi/pdf/10.1021/ja9640354

Reference72 articles.

1. Characterization of the first examples of isolable molecular hydrogen complexes, M(CO)3(PR3)2(H2) (M = molybdenum or tungsten; R = Cy or isopropyl). Evidence for a side-on bonded dihydrogen ligand

2. Molecular hydrogen complexes: coordination of a .sigma. bond to transition metals

3. Dihydrogen complexes: some structural and chemical studies

4. Reactions of transition metal dihydrogen complexes

5. Coordination chemistry of dihydrogen

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