Stereochemical Relay through a Cationic Intermediate: Helical Preorganization Dictates Direction of Conrotation in the halo-Nazarov Cyclization
Author:
Affiliation:
1. Department of Chemistry, University of Rochester, 414 Hutchison Hall, 100 Trustee Road, Rochester, New York 14627-0216, United States
Funder
Division of Chemistry
American Chemical Society Petroleum Research Fund
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.0c01330
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1. Axial-to-central chirality transfer in cyclization processes
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4. The Role of Bent Acyclic Allene Gold Complexes in Axis‐to‐Center Chirality Transfers
5. A short enantioselective synthesis of (+)-sterpurene: complete intramolecular transfer of central to axial to central chiral elements
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