A General Copper-Catalyzed Synthesis of Ynamides from 1,2-Dichloroenamides
Author:
Affiliation:
1. Chemistry Research Laboratory, 12 Mansfield Road, Oxford, OX1 3TA, U.K.
2. Janssen PRD, 3210 Merryfield Row, San Diego, California 92121, United States
Funder
Janssen Pharmaceuticals
Defence Science and Technology Laboratory
AstraZeneca
Novartis
Engineering and Physical Sciences Research Council
Takeda Pharmaceutical Company
Pfizer
Vertex Pharmaceuticals
University of Oxford
UCB
GlaxoSmithKline
Evotec
Syngenta
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.9b00971
Reference68 articles.
1. Umpolung Reactivity of Ynamides: An Unconventional [1,3]‐Sulfonyl and [1,5]‐Sulfinyl Migration Cascade
2. Alkyne Versus Ynamide Reactivity: Regioselective Radical Cyclization of Yne‐Ynamides
3. Stereodivergent synthesis of 1,4-dicarbonyls by traceless charge–accelerated sulfonium rearrangement
4. Metal-Free Cyclization of ortho -Nitroaryl Ynamides and Ynamines towards Spiropseudoindoxyls
5. Palladium-Catalyzed Oxygenative Cross-Coupling of Ynamides and Benzyl Bromides by Carbene Migratory Insertion
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