Kinetic Resolution of Nearly Symmetric 3-Cyclohexene-1-carboxylate Esters Using a Bacterial Carboxylesterase Identified by Genome Mining
Author:
Affiliation:
1. The Key Laboratory of Industrial Biotechnology, School of Biotechnology, Jiangnan University, Wuxi 214122, P. R. China
2. Graduate School of Engineering, Muroran Institute of Technology, 27-1, Mizumoto-cho, Muroran, Hokkaido 050-8585, Japan
Funder
State Administration of Foreign Experts Affairs
Ministry of Education of the People's Republic of China
Ministry of Science and Technology of the People's Republic of China
Government of Jiangsu Province
National Natural Science Foundation of China
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.1c00714
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1. Practical, asymmetric synthesis of the cyclohexyl C28-C34 fragment of the immunosuppressant FK-506 via (S)-(−)-3-cyclohexenecarboxylic acid
2. An asymmetric synthesis of (+)-phyllanthocin
3. Synthesis of (-)-periplanone-B a sex pheromone component of the American cockroach (periplaneta americana)
4. Synthesis of both the enantiomers of hauptmann's periplanone-A and clarification of the structure of Persoons's periplanone-A
5. Stereoselective Transformation of Enantiopure Cyclohexenol into cis-Hydrindan. An Enantioselective Formal Total Synthetic Route to (+)-Pumiliotoxin C
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