Zinc-Catalyzed Synthesis of Acylsilanes Using Carboxylic Acids and a Silylborane in the Presence of Pivalic Anhydride
Author:
Affiliation:
1. Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto 615-8510, Japan
Funder
Tokuyama Science Foundation
Japan Society for the Promotion of Science
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.9b04151
Reference46 articles.
1. Acylsilanes: valuable organosilicon reagents in organic synthesis
2. Silyl ketone chemistry. A new regiospecific route to silyl enol ethers
3. 1-Trimethylsilylallylic alcohols as homoenolate precursors. Stereo- and regio-specific synthesis of silyl enol ethers
4. Reaction of .beta.-heteroatom-substituted .alpha.,.beta.-unsaturated acylsilanes with ketone enolates: a new [3+2] annulation based on the Brook rearrangement
5. [3 + 4] Annulation of α,β-Unsaturated Acylsilanes with Enolates of α,β-Unsaturated Methyl Ketones: Scope and Mechanism
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