Stereoselective Synthesis of Trisubstituted Alkenylboron Reagents by Boron-Wittig Reaction of Ketones
Author:
Affiliation:
1. Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467, United States
Funder
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.orglett.9b01663
Reference14 articles.
1. Hindered organoboron groups in organic chemistry. 23. The interactions of dimesitylboron stabilised carbanions with aromatic ketones and aldehydes to give alkenes.
2. Deprotonation of 1,1-diboronic esters and reactions of the carbanions with alkyl halides and carbonyl compounds
3. Reaction of aldehydes and ketones with a boron-substituted carbanion, bis(ethylenedioxyboryl)methide. Simple aldehyde homologation
4. Lithium bis(ethylenedioxyboryl)methide and its reactions with carbonyl compounds and with the chlorotriphenyl derivatives of germanium, tin and lead
5. Carbanions from deprotonation of gem-diboronic esters
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