Unusual Formation and Reactivity of a Diplatinum μ-Phenylethenylidene Complex: Synthesis and Structures of cis,cis-[(PPh3)(C6F5)2Pt(μ-η1:η3-CHPhCCO)Pt(PPh3)2] and cis,cis-[(PPh3)2Pt{μ-η2(C,S):η1(C)-C(SPh)(CH2Ph)}Pt(C6F5)2(CO)] Dinuclear Compounds-Reference-Cited by-同舟云学术

Unusual Formation and Reactivity of a Diplatinum μ-Phenylethenylidene Complex: Synthesis and Structures of cis,cis-[(PPh3)(C6F5)2Pt(μ-η1:η3-CHPhCCO)Pt(PPh3)2] and cis,cis-[(PPh3)2Pt{μ-η2(C,S):η1(C)-C(SPh)(CH2Ph)}Pt(C6F5)2(CO)] Dinuclear Compounds

Published:1996-02-06 Issue:3 Volume:15 Page:1014-1022
ISSN:0276-7333
Container-title:Organometallics
language:en
Short-container-title:Organometallics

Author:

Ara Irene¹,Berenguer Jesús R.¹,Forniés Juan¹,Lalinde Elena¹,Tomás Milagros¹

Affiliation:

1. Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain, and Departamento de Química, Universidad de La Rioja, 26001 Logroño, Spain

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/om950891x

Reference99 articles.

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2. Vinylidene and Propadienylidene (Allenylidene) Metal Complexes

3. Organometallic chemistry of vinylidene and related unsaturated carbenes

4. Reactivity of 1-alkynes at dimanganese carbonyl centers. Synthesis and structural characterization of alkenyl-, alkenylidene-, alkynyl-, and 5-oxo-2-furanylidene-bridged dimanganese compounds

5. Reactions of co-ordinated ligands. Part 53. Synthesis of dimolybdenum and ditungsten µ-σ,η2-(4e)-vinylidene and -allenylidene complexes; crystal structures of [N(PPh3)2][Mo2{µ-σ:η2-(3e)-C2Ph}(CO)4(η5-C9H7)2], [Mo2{µ-σ:η2-(4e)-CC(Ph)(CH2)4OMe}(CO)4(η-C5H5)2] and [Mo2{µ-σ:η2-(4e)-CCCMe2}(CO)4(η-C5H5)2]

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